Sulfide stress corrosion cracking of steels corrosion. Stress corrosion cracking of a low alloy steel in hot. Stress corrosion cracking susceptibility of low alloy. Tice stress corrosion in low alloy steels and very rarely in reactor pressure vessels themselves. Bulloch electricity supply board, lower fitzwilliam street, dublin 2, ireland the present report attempts to describe a stress corrosion cracking, scc, study conducted on steels of varying carbon content in a.
Stress corrosion cracking of a low alloy steel to stainless steel transition weld in pwr primary waters at 2928c. For four low alloy steels with a wide range of tensile strengths, the dynamical processes of the nucleation and propagation of stress corrosion cracking scc in water with various polarization conditions and in a inhibitor solution were traced with an optical microscope. Stress corrosion cracking scc in passivating environments. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking behavior in the transition. Stress corrosion cracking behavior around interface. Stress corrosion cracking behavior of nickel base alloys. Either electroplated or hotdip zinc coatings decrease resistance to stress corrosion cracking, i.
Many research works have been done to study the single solution parameter effect on the stress corrosion cracking, such as h 2 s concentration or cl. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Stress corrosion cracking of highstrength steels in. Sulfide stress corrosion of some medium and low alloy. Stress corrosion in low alloy steels sciencedirect. Susceptibility to caustic scc depends on several variables including alloy content, caustic concentration, temperature, and stress. Avoiding stress corrosion cracking of carbon low alloy and. This paper is related to the new stress corrosion cracking phenomenon of mild and low alloy steels in a coco 2 environment. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. The stress corrosion cracking scc behavior perpendicular to the fusion line in the transition region between the alloy 182 nickelbase weld metal and the adjacent lowalloy reactor pressure vessel rpv steel of simulated dissimilar metal weld joints was investigated under boilingwater reactor normalwater chemistry conditions at different stress intensities and chloride.
The stress corrosion cracking scc behaviour of lowalloy, reactorpressurevessel rpv steels in oxygenated, hightemperature water and its relevance to boiling water reactor bwr power operation, in particular its possible effect on both rpv structural integrity and safety, has been a subject of controversial discussions for many years. As a result of the increasingly high strength and harsh service conditions, hsla steel inevitably experiences the challenge of stress corrosion cracking scc, particularly in. As a general rule, the resistance to caustic solutions increases with increasing nickel content. Stress corrosion cracking of lowalloy, reactorpressure. Alloys based on nickel, copper, aluminum, magnesium, etc. Highnickel alloys abrass aluminum alloys titanium alloys magnesium alloys zirconium alloys environment hot nitrate, hydroxide, and. Either electroplated or hotdip zinc coatings decrease resistance to stress corrosion cracking,i. Factors governing stress corrosion cracking scc of low strength, low alloy nickel steels e. Scc usually occurs in certain specific alloy environment stress combinations.
Studies have been done on stress corrosion cracking scc susceptibility of low alloy steels in water containing dissolved oxygen. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The stress corrosion cracking scc behavior of three different nuclear grade reactor pressure vessel rpv steels sa 533 b cl. Stress corrosion cracking of low alloy steels in natural.
Transgranular stress corrosion cracking of lowalloy. Stress corrosion cracking international institute of. In this chapter, the conditions for the occurrence of scc are first introduced. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will. Effects of nb on stress corrosion cracking of high. Review of nickels role in sulfide stress cracking of low alloy steels. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. For four lowalloy steels with a wide range of tensile strength, the dynamical processes of the nucleation and propagation of stress corrosion cracking scc in water with various polarization conditions and in a 0. The fundamental factors which affect the scc susceptibility were clarified, and the integrity of the reactor pressure vessel rpv, in which these steels are used, was assessed from the standpoint of scc initiation.
Effects of zinc coatings on the stress corrosion cracking and hydrogen embrittlement of low alloy steel article pdf available in metallurgical and materials transactions a 64. Effects of zinc coatings on the stress corrosion cracking. A study made of factors influencing sulfidestress corrosion of a number of low alloy and medium alloy steels showed that their delayed failures when exposed simultaneously to stress and the corrosive action of acidified brinehydrogen sulfide solutions have most of the features of hydrogen induced, delayed brittle failures. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stress corrosion cracking scc in aircontaminated dry ammonia. The role of hydrogen in sulfide stress cracking of low. Stress corrosion cracking scc is a common issue with many specialty alloys. Stress corrosion cracking of the highstrength martensitic steel aisi 4340 yield stress 1503mpa in nacl aqueous solutions of different concentrations was studied experimentally using compact. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Effects of temperature, dissolved oxygen do content, and direction of. This new second edition serves as a goto reference on the complex subject of stress corrosion cracking scc, offering information to help metallurgists, materials scientists, and designers determine whether scc will be an issue for their design or application. Low alloy steels are less susceptible than high alloy steels, but they are subject to scc in water containing chloride ions. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion.
Stress corrosion cracking scc results from the combined action of stress, a cracking electrochemical environment, and temperature to cause cracks to initiate and grow in susceptible steel. The structure of tempered martensite and its susceptibility to hydrogen stress cracking. For these quenched and tempered, high strength, low alloy steels, the susceptibility to co2 scc increased with dissolved oxygen, co2 partial pressure, and yield stress. Pdf stresscorrosion cracking of aisi 4340 steel in.
In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Sulfide stress cracking of nickelcontaining lowalloy. High strength low alloy hsla corrosion carbon steel can be alloyed, singly or in combination, with chromium, nickel, copper, molybdenum, phosphorus, and vanadium in the range of a few percent or less to produce high strength low alloy hsla steels. Susceptibility of lowalloy carbon steel to pitting and. Nevertheless, rare instances of environmentally assisted cracking have oc curred, more often in pipework than in pressure vessels 410 p. The scc in the transition zone was mainly intergranular in the austenitic layer, but transgranular cracking occurred at the interface and in the low alloy steel. Stress corrosion cracking of a low alloy steel to stainless steel transition weld in pwr primary waters at 2928c free download as pdf file. Individual cracks are generally oriented perpendicular to the maximum stress and parallel to the tube pipe axis. The effects of electroplated and hotdip zinc coatings on the fracture of low alloy steel aisi 4140 bars tempered to hardnesses in the range rc 33 to 49 were studied. Avoiding stress corrosion cracking of carbon low alloy and austenitic stainless steels in chloride and caustic environments synopsis this maintenance best practice guide is concerned with the performance of carbon and low alloy steels, and austenitic stainless steels, in chloride and caustic containing fluids. The stress corrosion cracking susceptibilities of type 16mnr low alloy steel in simulated oil refining environment were investigated by slow strain rate test. In water, severe pitting of the steel may occur if large amounts of millscale are present on the surface.
Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Stress corrosion cracking of low strength, low alloy. Theoretical and applied fracture mechanics 16 1991 117 1 elsevier stress corrosion cracking of low alloy steels in natural seawater environment the influence of carbon level j. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Carbon and low alloy steels can suffer from scc in a wide range of environments that tend to form a. The incidents of cracking are described and these were reproduced by laboratory tests. The weld was postweldheattreated at 620c for 20 h before testing.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. A modified middle scaled creviced bent beam cbb test was conducted in order to investigate stress corrosion cracking scc behavior around fusion boundary between nickel base alloy alloy82 and low alloy steel las under high stress conditions in light water reactor lwr coolant environment. The minimum potential for scc, in each water used was higher than the free corrosion potential range of. The effects of electrode potential and sulphate so 2. Stresscorrosion cracking of steels in ammonia with. The buildup of corrosion products in confined spaces can also generate significant stresses and should not be overlooked. Investigation of stress corrosion cracking of lowalloy. Stress corrosion cracking of mild and low alloy steels in. Parameters that control stress corrosion cracking scc and conditions under which it can occur. Stress corrosion cracking susceptibility of type 16mnr low. The stress corrosion cracking scc behaviour of low alloy, reactorpressurevessel rpv steels in oxygenated, hightemperature water and its relevance to boiling water reactor bwr power operation, in particular its possible effect on both rpv structural integrity and safety, has been a subject of controversial discussions for many years. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion.
519 175 1598 178 629 189 1214 1629 896 1603 1577 586 1263 407 464 422 627 319 766 254 1628 964 631 243 1647 1645 229 1069 1160 1170 210 908 737 686 1446 296 1286 170 242 469 565 1241 458 149 809